Thursday, June 9, 2011

Announcements:

Assignments:

Chapter 16:  Temperature and Heat

Temperature scales:
    T(Kelvin) = T(Celsius) + 273.15
    T(Fahrenheit) = (9/5)T(Celsius) + 32

Heat is a transfer of energy due to a temperature difference.
A calorie is the amount of heat needed to raise the temperature of 1 g of water from 14.5o to 15.5o C.
1 Calorie = 1 kcal
The mechanical equivalent of heat is 4.186 J/cal.
The heat (Q) required to change the temperature of a substance by (dT) is Q = mc(dT), where m is the mass of the substance and c is its specific heat.
Water has one of the highest specific heats of any substance.  This means it can store a lot of thermal energy, and it also takes a lot of heat to change its temperature compared with other materials.

Heat can be transferred by 3 processes:

conduction - requires contact between materials:  Q/dt = kA(T2-T1)/L
convection - requires fluid, occurs naturally due to buoyant forces from density variations
radiation - all objects absorb and emit electromagnetic radiation (infrared)
The rate of radiation (radiating power) is given by Stefan's law:  P = sAeT^4.

Newton's law of cooling:  The rate that a substance cools (or warms) is proportional to the temperature difference between its temperature and the ambient temperature.

Most substances expand when heated, and the rate of expansion depends on the temperate difference and the linear, area, or volume expansion coefficient.

Ponderables:

Problems:

Demos:

Chapter 17 - Phases and Phase Changes

Ideal gas law:  PV = nRT   (Note specific cases:  Boyle's Law:  PV = constant, and Charles' Law: V/T = constant)

    Note:  Remember that T must be in Kelvin, and n = number of moles, and R is the universal gas constant.

The pressure of a gas is proportional to the average kinetic energy of the gas molecules (since the molecules are bouncing off the walls of the container), which is directly proportional to the absolute (Kelvin) temperature of the gas.  From this relationship, the average (rms) speed of the gas molecules can be calculated, and this is useful for determining whether a planet has an atmosphere based on the escape speed of each type of gas molecule.

Average kinetic energy of a gas:  Kav = (3/2)kT

RMS speed of a gas molecule:  v(rms) = sqrt(3kT/m) = sqrt(3RT/M)

Internal energy of a monatomic ideal gas: U = (3/2)NkT = (3/2)nRT

The heat required to change the phase of a mass is Q = mL, where L is the latent heat of fusion (Lf), vaporization (Lv), or sublimation (Ls).

Solids and Elastic Deformation:

Elastic modulus = stress/strain
Stress is proportional to force exerted and has same units as pressure.
Strain is a measure of degree of deformation.
1D - Young's modulus, Y
2D - Shear modulus, S
3D - Bulk modulus, B
Elastic deformation is where the solid returns to its original size and shape when the stress is removed.  Most materials have an elastic range, but when stresses exceed the elastic limit, the object becomes permanently deformed or breaks.

Review question:  A Galileo thermometer consists of several sealed glass spheres of various specific gravities in a water column.  What will happen when the temperature rises?

Balloon demo and questions relating the ideal gas law with fluid physics: